Limits...
Cp 2 TiCl/D 2 O/Mn, a formidable reagent for the deuteration of organic compounds

View Article: PubMed Central - HTML - PubMed

ABSTRACT

Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to different functional groups and can contribute to the synthesis of new deuterated organic compounds under friendly experimental conditions and with great economic advantages.

No MeSH data available.


Examples of deuterations of organic compounds using Cp2TiCl/D2O/Mn. aSubstoichiometric amount of Cp2TiCl; D: deuterium incorporation.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
getmorefigures.php?uid=PMC4979672&req=5

C3: Examples of deuterations of organic compounds using Cp2TiCl/D2O/Mn. aSubstoichiometric amount of Cp2TiCl; D: deuterium incorporation.

Mentions: In any case, apart from mechanistic considerations, the Cp2TiCl/D2O/Mn mixture has emerged as an excellent reagent for the deuteration of organic compounds from epoxides [2,27,37], ozonides [29], ketones [31–32], activated halides [30–32], alkenes and alkynes [33]. Several examples are presented in Scheme 3.


Cp 2 TiCl/D 2 O/Mn, a formidable reagent for the deuteration of organic compounds
Examples of deuterations of organic compounds using Cp2TiCl/D2O/Mn. aSubstoichiometric amount of Cp2TiCl; D: deuterium incorporation.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979672&req=5

C3: Examples of deuterations of organic compounds using Cp2TiCl/D2O/Mn. aSubstoichiometric amount of Cp2TiCl; D: deuterium incorporation.
Mentions: In any case, apart from mechanistic considerations, the Cp2TiCl/D2O/Mn mixture has emerged as an excellent reagent for the deuteration of organic compounds from epoxides [2,27,37], ozonides [29], ketones [31–32], activated halides [30–32], alkenes and alkynes [33]. Several examples are presented in Scheme 3.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

Cp2TiCl/D2O/Mn is an efficient combination, sustainable and cheap reagent that mediates the D-atom transfer from D2O to different functional groups and can contribute to the synthesis of new deuterated organic compounds under friendly experimental conditions and with great economic advantages.

No MeSH data available.