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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The reduction and rearrangements of isoprostanes.
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C183: The reduction and rearrangements of isoprostanes.

Mentions: The formation of the metabolites isoprostanes, neuroprostanes, phytoprostanes, and isofurans 655–657 from fatty acids under autoxidative conditions in vivo involves both the reduction of peroxides and their rearrangements (Scheme 183). These compounds proved to be widespread in nature. Compounds 655–657 display significant biological activities, and the isoprostanes are currently the most reliable indicators of oxidative stress [568–570].


Rearrangements of organic peroxides and related processes
The reduction and rearrangements of isoprostanes.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C183: The reduction and rearrangements of isoprostanes.
Mentions: The formation of the metabolites isoprostanes, neuroprostanes, phytoprostanes, and isofurans 655–657 from fatty acids under autoxidative conditions in vivo involves both the reduction of peroxides and their rearrangements (Scheme 183). These compounds proved to be widespread in nature. Compounds 655–657 display significant biological activities, and the isoprostanes are currently the most reliable indicators of oxidative stress [568–570].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.