Limits...
Rearrangements of organic peroxides and related processes

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
getmorefigures.php?uid=PMC4979652&req=5

C170: The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g.

Mentions: The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g involves the formation of intermediate radicals 608a,b, the structures of which differ from that of the radicals generated by photolysis or thermal decomposition. Ruthenium ions have a considerable effect on the stability and reactivity of radicals, resulting in the selective transformation of peroxides under mild conditions. The reactivity also substantially depends on steric factors (Scheme 170) [503,520–521].


Rearrangements of organic peroxides and related processes
The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C170: The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g.
Mentions: The Ru(II)-catalyzed reactions of 1,4-endoperoxide 261g involves the formation of intermediate radicals 608a,b, the structures of which differ from that of the radicals generated by photolysis or thermal decomposition. Ruthenium ions have a considerable effect on the stability and reactivity of radicals, resulting in the selective transformation of peroxides under mild conditions. The reactivity also substantially depends on steric factors (Scheme 170) [503,520–521].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.