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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

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The CoTPP-catalyzed transformation of epoxy-1,2-dioxanes.
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C169: The CoTPP-catalyzed transformation of epoxy-1,2-dioxanes.

Mentions: The reaction of epoxy-1,2-dioxanes 604a–d and 606 with Co(II) complexes affords 4-hydroxy-2,3-epoxy ketones 605a–d and 607 in good yields (Scheme 169) [364]. Possibly the selectivity towards the hydroxyketones formation is provided by means of cobalt ions interaction. The obtained compounds are useful synthons in organic synthesis.


Rearrangements of organic peroxides and related processes
The CoTPP-catalyzed transformation of epoxy-1,2-dioxanes.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C169: The CoTPP-catalyzed transformation of epoxy-1,2-dioxanes.
Mentions: The reaction of epoxy-1,2-dioxanes 604a–d and 606 with Co(II) complexes affords 4-hydroxy-2,3-epoxy ketones 605a–d and 607 in good yields (Scheme 169) [364]. Possibly the selectivity towards the hydroxyketones formation is provided by means of cobalt ions interaction. The obtained compounds are useful synthons in organic synthesis.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Related in: MedlinePlus