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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

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Fe(II) cysteinate-promoted transformation of tetraoxane 574.
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C167: Fe(II) cysteinate-promoted transformation of tetraoxane 574.

Mentions: The reaction of synthetic tetraoxane 574 with Fe(II) cysteinate affords a complex mixture of products. Only one product, 575, could be isolated from the mixture and identified. This was the first work, where the Fe(II)-promoted cleavage of 1,2,4,5-tetraoxane was investigated (Scheme 167) [508].


Rearrangements of organic peroxides and related processes
Fe(II) cysteinate-promoted transformation of tetraoxane 574.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C167: Fe(II) cysteinate-promoted transformation of tetraoxane 574.
Mentions: The reaction of synthetic tetraoxane 574 with Fe(II) cysteinate affords a complex mixture of products. Only one product, 575, could be isolated from the mixture and identified. This was the first work, where the Fe(II)-promoted cleavage of 1,2,4,5-tetraoxane was investigated (Scheme 167) [508].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Related in: MedlinePlus