Limits...
Rearrangements of organic peroxides and related processes

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The Story decomposition of cyclic triperoxide 506b.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
getmorefigures.php?uid=PMC4979652&req=5

C147: The Story decomposition of cyclic triperoxide 506b.

Mentions: Story and co-workers discovered that the thermal and photochemical decomposition of cyclic ketone peroxides 506 produces cycloalkanes 507 and cyclic lactones 508 (Scheme 146 and Scheme 147) [480–483]. This transformation is a general method for the synthesis of macrocyclic compounds from readily available starting materials.


Rearrangements of organic peroxides and related processes
The Story decomposition of cyclic triperoxide 506b.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C147: The Story decomposition of cyclic triperoxide 506b.
Mentions: Story and co-workers discovered that the thermal and photochemical decomposition of cyclic ketone peroxides 506 produces cycloalkanes 507 and cyclic lactones 508 (Scheme 146 and Scheme 147) [480–483]. This transformation is a general method for the synthesis of macrocyclic compounds from readily available starting materials.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.