Limits...
Rearrangements of organic peroxides and related processes

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Synthesis of esters 503 from aldehydes 501 via rearrangement of peroxides 502.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
getmorefigures.php?uid=PMC4979652&req=5

C144: Synthesis of esters 503 from aldehydes 501 via rearrangement of peroxides 502.

Mentions: An intramolecular rearrangement of α-azidoperoxides 502 promoted by DBU provides esters 503. The reaction takes place with alkyl, aryl and heteroaryl α-azidoperoxides generated from the corresponding aldehydes 501 (Scheme 144) [479].


Rearrangements of organic peroxides and related processes
Synthesis of esters 503 from aldehydes 501 via rearrangement of peroxides 502.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C144: Synthesis of esters 503 from aldehydes 501 via rearrangement of peroxides 502.
Mentions: An intramolecular rearrangement of α-azidoperoxides 502 promoted by DBU provides esters 503. The reaction takes place with alkyl, aryl and heteroaryl α-azidoperoxides generated from the corresponding aldehydes 501 (Scheme 144) [479].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.