Limits...
Rearrangements of organic peroxides and related processes

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Related in: MedlinePlus

The mechanism of the transformation of (tert-butyldioxy)cyclohexanedienones 472.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
getmorefigures.php?uid=PMC4979652&req=5

C136: The mechanism of the transformation of (tert-butyldioxy)cyclohexanedienones 472.

Mentions: The TiCl4-promoted rearrangement of (tert-butyldioxy)cyclohexanedienones 472a–d, which are generated by the ruthenium-catalyzed oxidation of phenols with tert-butyl hydroperoxide, provides an efficient route to 2-substituted quinones 473a–d (Table 21) [453–454]. The mechanism of this transformation is depicted in Scheme 136.


Rearrangements of organic peroxides and related processes
The mechanism of the transformation of (tert-butyldioxy)cyclohexanedienones 472.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C136: The mechanism of the transformation of (tert-butyldioxy)cyclohexanedienones 472.
Mentions: The TiCl4-promoted rearrangement of (tert-butyldioxy)cyclohexanedienones 472a–d, which are generated by the ruthenium-catalyzed oxidation of phenols with tert-butyl hydroperoxide, provides an efficient route to 2-substituted quinones 473a–d (Table 21) [453–454]. The mechanism of this transformation is depicted in Scheme 136.

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Related in: MedlinePlus