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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The acid-catalyzed oxidative rearrangement of malondialdehydes 462 under the action of H2O2.
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C134: The acid-catalyzed oxidative rearrangement of malondialdehydes 462 under the action of H2O2.

Mentions: Carboxylic acids 464 were prepared through a camphorsulfonic acid-catalyzed oxidative rearrangement of a 1,2-dioxolane intermediate 463 prepared from malondialdehydes 462 and H2O2 (Scheme 134) [451].


Rearrangements of organic peroxides and related processes
The acid-catalyzed oxidative rearrangement of malondialdehydes 462 under the action of H2O2.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C134: The acid-catalyzed oxidative rearrangement of malondialdehydes 462 under the action of H2O2.
Mentions: Carboxylic acids 464 were prepared through a camphorsulfonic acid-catalyzed oxidative rearrangement of a 1,2-dioxolane intermediate 463 prepared from malondialdehydes 462 and H2O2 (Scheme 134) [451].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.