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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Trapping of dioxacyclopentyl radical 392 by oxygen.
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C118: Trapping of dioxacyclopentyl radical 392 by oxygen.

Mentions: However, this process was not observed and none of the possible carbon-centered radicals 390 was trapped by molecular oxygen [414]. Meanwhile, it is known that the dioxacyclopentyl radical 392 formed from 391 is trapped by oxygen to form hydroperoxide 393 (Scheme 118) [415].


Rearrangements of organic peroxides and related processes
Trapping of dioxacyclopentyl radical 392 by oxygen.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C118: Trapping of dioxacyclopentyl radical 392 by oxygen.
Mentions: However, this process was not observed and none of the possible carbon-centered radicals 390 was trapped by molecular oxygen [414]. Meanwhile, it is known that the dioxacyclopentyl radical 392 formed from 391 is trapped by oxygen to form hydroperoxide 393 (Scheme 118) [415].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.