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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The Kornblum–DeLaMare rearrangement as one step in the oxidation reaction of enamines.
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C84: The Kornblum–DeLaMare rearrangement as one step in the oxidation reaction of enamines.

Mentions: In the case of acyclic enamine 278, the initial dioxetane product from the photochemical oxidation of 279 rearranged to amide 280. The reactions using cyclic enamines 281 involve the Kornblum–DeLaMare rearrangement of dioxetanes 282 into 1,2-diketones 283 (Scheme 84) [359–360].


Rearrangements of organic peroxides and related processes
The Kornblum–DeLaMare rearrangement as one step in the oxidation reaction of enamines.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C84: The Kornblum–DeLaMare rearrangement as one step in the oxidation reaction of enamines.
Mentions: In the case of acyclic enamine 278, the initial dioxetane product from the photochemical oxidation of 279 rearranged to amide 280. The reactions using cyclic enamines 281 involve the Kornblum–DeLaMare rearrangement of dioxetanes 282 into 1,2-diketones 283 (Scheme 84) [359–360].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.