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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


Synthesis of diaryl carbonates 160a–d from triarylmethanols 159a–d through successive oxygen insertion.
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C47: Synthesis of diaryl carbonates 160a–d from triarylmethanols 159a–d through successive oxygen insertion.

Mentions: This method for the insertion of an oxygen atom was applied to the oxidation of triarylmethanols 159a–d [299]. The successive insertion of oxygen atoms gave rise to diaryl carbonates 160a–d in good yields (Scheme 47).


Rearrangements of organic peroxides and related processes
Synthesis of diaryl carbonates 160a–d from triarylmethanols 159a–d through successive oxygen insertion.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C47: Synthesis of diaryl carbonates 160a–d from triarylmethanols 159a–d through successive oxygen insertion.
Mentions: This method for the insertion of an oxygen atom was applied to the oxidation of triarylmethanols 159a–d [299]. The successive insertion of oxygen atoms gave rise to diaryl carbonates 160a–d in good yields (Scheme 47).

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.