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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The Baeyer–Villiger oxidation of the fully substituted pyrrole 120.
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C36: The Baeyer–Villiger oxidation of the fully substituted pyrrole 120.

Mentions: The sterically hindered and fully substituted pyrrole 120 underwent a Baeyer–Villiger reaction to yield a 4,5-dihydro-1H-ketopyrrole 121 (Scheme 36) [289].


Rearrangements of organic peroxides and related processes
The Baeyer–Villiger oxidation of the fully substituted pyrrole 120.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C36: The Baeyer–Villiger oxidation of the fully substituted pyrrole 120.
Mentions: The sterically hindered and fully substituted pyrrole 120 underwent a Baeyer–Villiger reaction to yield a 4,5-dihydro-1H-ketopyrrole 121 (Scheme 36) [289].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.