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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The mechanism of the asymmetric oxidation of 3-substituted cyclobutanone 96a in the presence of chiral phosphoric acid.
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C31: The mechanism of the asymmetric oxidation of 3-substituted cyclobutanone 96a in the presence of chiral phosphoric acid.

Mentions: Possible mechanisms for the asymmetric oxidation of 3-substituted cyclobutanone 96a with H2O2 catalyzed by chiral phosphoric acid are presented in Scheme 31 [275].


Rearrangements of organic peroxides and related processes
The mechanism of the asymmetric oxidation of 3-substituted cyclobutanone 96a in the presence of chiral phosphoric acid.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C31: The mechanism of the asymmetric oxidation of 3-substituted cyclobutanone 96a in the presence of chiral phosphoric acid.
Mentions: Possible mechanisms for the asymmetric oxidation of 3-substituted cyclobutanone 96a with H2O2 catalyzed by chiral phosphoric acid are presented in Scheme 31 [275].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.