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Rearrangements of organic peroxides and related processes

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ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.


The Baeyer–Villiger oxidation of ketones 45 using diaryl diselenide and hydrogen peroxide.
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C14: The Baeyer–Villiger oxidation of ketones 45 using diaryl diselenide and hydrogen peroxide.

Mentions: In the first step of the catalytic cycle of the Baeyer–Villiger oxidation using diaryl diselenide 50 and hydrogen peroxide seleninic acid 51 is generated, which is then oxidized to perseleninic acid 52. Oxidation of the ketone 45 by perseleninic acid 52 involves the intermediate peroxide 53 (Scheme 14) [235].


Rearrangements of organic peroxides and related processes
The Baeyer–Villiger oxidation of ketones 45 using diaryl diselenide and hydrogen peroxide.
© Copyright Policy - Beilstein
Related In: Results  -  Collection

License 1 - License 2
Show All Figures
getmorefigures.php?uid=PMC4979652&req=5

C14: The Baeyer–Villiger oxidation of ketones 45 using diaryl diselenide and hydrogen peroxide.
Mentions: In the first step of the catalytic cycle of the Baeyer–Villiger oxidation using diaryl diselenide 50 and hydrogen peroxide seleninic acid 51 is generated, which is then oxidized to perseleninic acid 52. Oxidation of the ketone 45 by perseleninic acid 52 involves the intermediate peroxide 53 (Scheme 14) [235].

View Article: PubMed Central - HTML - PubMed

ABSTRACT

This review is the first to collate and summarize main data on named and unnamed rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides two types of processes are considered under the term rearrangements. These are conventional rearrangements occurring with the retention of the molecular weight and transformations of one of the peroxide moieties after O–O-bond cleavage. Detailed information about the Baeyer−Villiger, Criegee, Hock, Kornblum−DeLaMare, Dakin, Elbs, Schenck, Smith, Wieland, and Story reactions is given. Unnamed rearrangements of organic peroxides and related processes are also analyzed. The rearrangements and related processes of important natural and synthetic peroxides are discussed separately.

No MeSH data available.