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Crystal structure of bis-{1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(3) O,N (2),O'}copper(II) containing an unknown solvate.

Chetioui S, Hamdouni N, Rouag DA, Bouaoud SE, Merazig H - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: Each Cu(II) atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olate ligands.C71, 9-18].Their formula mass and unit-cell characteristics were not taken into account during refinement.

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Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Constantine 25000, Algeria.

ABSTRACT
The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent mol-ecules in the asymmetric unit. Each Cu(II) atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olate ligands. In the crystal, the two mol-ecules are linked via weak C-H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9-18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of (I), with displacement ellipsoids for non-H atoms shown at 50% probability.
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Fap1: The molecular structure of (I), with displacement ellipsoids for non-H atoms shown at 50% probability.


Crystal structure of bis-{1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olato-κ(3) O,N (2),O'}copper(II) containing an unknown solvate.

Chetioui S, Hamdouni N, Rouag DA, Bouaoud SE, Merazig H - Acta Crystallogr E Crystallogr Commun (2015)

The molecular structure of (I), with displacement ellipsoids for non-H atoms shown at 50% probability.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645079&req=5

Fap1: The molecular structure of (I), with displacement ellipsoids for non-H atoms shown at 50% probability.
Bottom Line: Each Cu(II) atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olate ligands.C71, 9-18].Their formula mass and unit-cell characteristics were not taken into account during refinement.

View Article: PubMed Central - HTML - PubMed

Affiliation: Unité de Recherche de Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Département de Chimie, Université Constantine 1, Constantine 25000, Algeria.

ABSTRACT
The title complex, [Cu(C17H13N2O2)2], crystallizes with two independent mol-ecules in the asymmetric unit. Each Cu(II) atom has a distorted ocahedral coordination environment defined by two N atoms and four O atoms from two tridentate 1-[(E)-(2-meth-oxy-phen-yl)diazen-yl]naphthalen-2-olate ligands. In the crystal, the two mol-ecules are linked via weak C-H⋯O hydrogen bonds which in turn stack parallel to [010]. A region of disordered electron density, most probably disordered methanol solvent molecules, was corrected for using the SQUEEZE routine in PLATON [Spek (2015). Acta Cryst. C71, 9-18]. Their formula mass and unit-cell characteristics were not taken into account during refinement.

No MeSH data available.


Related in: MedlinePlus