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Crystal structure of di-chlorido-bis-[2-(phenyl-diazen-yl)pyridine-κN (1)]zinc.

Vittaya L, Leesakul N, Saithong S, Chainok K - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry.The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation.The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Science and Fisheries Technology, Rajamangala University of Technology Srivijaya, Sikao, Trang 92150, Thailand.

ABSTRACT
The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

No MeSH data available.


Related in: MedlinePlus

The arrangement of two-dimensional layers plotted down the a axis showing a lateral view of alternating C···Cl contact directions of adjacent sheets (A and B layers). H atoms are omitted for clarity.
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Fap4: The arrangement of two-dimensional layers plotted down the a axis showing a lateral view of alternating C···Cl contact directions of adjacent sheets (A and B layers). H atoms are omitted for clarity.


Crystal structure of di-chlorido-bis-[2-(phenyl-diazen-yl)pyridine-κN (1)]zinc.

Vittaya L, Leesakul N, Saithong S, Chainok K - Acta Crystallogr E Crystallogr Commun (2015)

The arrangement of two-dimensional layers plotted down the a axis showing a lateral view of alternating C···Cl contact directions of adjacent sheets (A and B layers). H atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645076&req=5

Fap4: The arrangement of two-dimensional layers plotted down the a axis showing a lateral view of alternating C···Cl contact directions of adjacent sheets (A and B layers). H atoms are omitted for clarity.
Bottom Line: The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry.The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation.The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Faculty of Science and Fisheries Technology, Rajamangala University of Technology Srivijaya, Sikao, Trang 92150, Thailand.

ABSTRACT
The structure of the title complex, [ZnCl2(C11H9N3)2], comprises two 2-(phenyl-diazen-yl)pyridine ligands coordin-ating to a central Zn(II) dichloride unit via the pyridyl N-atom donors, resulting in a slightly distorted tetra-hedral geometry. The complex exhibits twofold rotation symmetry, with the rotation axis bis-ecting the zinc cation. The structure is stabilized by weak inter-molecular C-H⋯Cl inter-actions [C⋯Cl = 3.411 (2) and 3.675 (2) Å], connecting neighbouring mol-ecules into layers perpendicular to the c axis.

No MeSH data available.


Related in: MedlinePlus