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Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate.

Nguyen VD, McCormick CA, Mague JT, Koplitz LV - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted.The crystal was refined as an inversion twin.

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Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.

ABSTRACT
The asymmetric unit of the title salt, C7H7N2 (+)·ClO4 (-), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra-molecular layers are stabilized and connected by C-H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

No MeSH data available.


Related in: MedlinePlus

Packing viewed down the b axis providing a plan view of the corrugated sheets with C—H···O interactions shown as dotted lines.
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Fap3: Packing viewed down the b axis providing a plan view of the corrugated sheets with C—H···O interactions shown as dotted lines.


Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate.

Nguyen VD, McCormick CA, Mague JT, Koplitz LV - Acta Crystallogr E Crystallogr Commun (2015)

Packing viewed down the b axis providing a plan view of the corrugated sheets with C—H···O interactions shown as dotted lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645073&req=5

Fap3: Packing viewed down the b axis providing a plan view of the corrugated sheets with C—H···O interactions shown as dotted lines.
Bottom Line: The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted.The crystal was refined as an inversion twin.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.

ABSTRACT
The asymmetric unit of the title salt, C7H7N2 (+)·ClO4 (-), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra-molecular layers are stabilized and connected by C-H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

No MeSH data available.


Related in: MedlinePlus