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Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate.
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The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted.The crystal was refined as an inversion twin.
Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.
ABSTRACT
The asymmetric unit of the title salt, C7H7N2 (+)·ClO4 (-), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra-molecular layers are stabilized and connected by C-H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin. No MeSH data available. Related in: MedlinePlus |
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Fap2: Packing viewed down the a axis showing an edge view of two corrugated layers and the C—H···O interaction (dotted line) holding them together. |
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Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.
No MeSH data available.
