Limits...
Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate.

Nguyen VD, McCormick CA, Mague JT, Koplitz LV - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted.The crystal was refined as an inversion twin.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.

ABSTRACT
The asymmetric unit of the title salt, C7H7N2 (+)·ClO4 (-), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra-molecular layers are stabilized and connected by C-H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

No MeSH data available.


Related in: MedlinePlus

Packing viewed down the a axis showing an edge view of two corrugated layers and the C—H···O interaction (dotted line) holding them together.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4645073&req=5

Fap2: Packing viewed down the a axis showing an edge view of two corrugated layers and the C—H···O interaction (dotted line) holding them together.


Crystal structure of 2-cyano-1-methyl-pyridinium perchlorate.

Nguyen VD, McCormick CA, Mague JT, Koplitz LV - Acta Crystallogr E Crystallogr Commun (2015)

Packing viewed down the a axis showing an edge view of two corrugated layers and the C—H···O interaction (dotted line) holding them together.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645073&req=5

Fap2: Packing viewed down the a axis showing an edge view of two corrugated layers and the C—H···O interaction (dotted line) holding them together.
Bottom Line: The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010).A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted.The crystal was refined as an inversion twin.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Loyola University, New Orleans, LA 70118, USA.

ABSTRACT
The asymmetric unit of the title salt, C7H7N2 (+)·ClO4 (-), comprises two independent formula units. The solid-state structure comprises corrugated layers of cations and of anions, approximately parallel to (010). The supra-molecular layers are stabilized and connected by C-H⋯O hydrogen bonding to consolidate a three-dimensional architecture. A close pyridin-ium-perchlorate N⋯O contact [2.867 (5) Å] is noted. The crystal was refined as an inversion twin.

No MeSH data available.


Related in: MedlinePlus