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Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu-thate(III)]-di-μ-iodido] dihydrate].

Touati Mel M, Elleuch S, Boughzala H - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing.The p-anisidinium cations and the water mol-ecules are located in the voids of the anionic sublattice.The cations are linked to each other through N-H⋯O hydrogen bonds with the water mol-ecules, and also through weaker N-H⋯I inter-actions to the anionic inorganic layers.

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Affiliation: Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia.

ABSTRACT
A new organic-inorganic hybrid material, {(C7H10NO)[BiI4]·2H2O} n , has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI6] octa-hedra sharing edges. The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing. The p-anisidinium cations and the water mol-ecules are located in the voids of the anionic sublattice. The cations are linked to each other through N-H⋯O hydrogen bonds with the water mol-ecules, and also through weaker N-H⋯I inter-actions to the anionic inorganic layers.

No MeSH data available.


The environment of the p-anisidinium cation in the structure of (C7H10NO)[BiI4]·2H2O. [Symmetry codes: (i) −x + , y − , −z + ; (ii)  − x, − + y,  − z.]
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fig4: The environment of the p-anisidinium cation in the structure of (C7H10NO)[BiI4]·2H2O. [Symmetry codes: (i) −x + , y − , −z + ; (ii)  − x, − + y,  − z.]

Mentions: The p-anisidinium cation is adopting a quite planar configuration characterized by a slight r.m.s. deviation of 0.020 (9) Å. Each p-anisidinium cation inter­acts with one [BiI6] octa­hedron via N—HA⋯I3i ( − x, − + y,  − z) , with two water mol­ecules by N—HB⋯OW1ii ( − x, − + y,  − z) and N—HC⋯OW2 hydrogen bonds (Table 2 ▸), as shown in Fig. 4 ▸.


Synthesis and structural studies of a new complex of catena-poly[p-anisidinium [[diiodidobismu-thate(III)]-di-μ-iodido] dihydrate].

Touati Mel M, Elleuch S, Boughzala H - Acta Crystallogr E Crystallogr Commun (2015)

The environment of the p-anisidinium cation in the structure of (C7H10NO)[BiI4]·2H2O. [Symmetry codes: (i) −x + , y − , −z + ; (ii)  − x, − + y,  − z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645070&req=5

fig4: The environment of the p-anisidinium cation in the structure of (C7H10NO)[BiI4]·2H2O. [Symmetry codes: (i) −x + , y − , −z + ; (ii)  − x, − + y,  − z.]
Mentions: The p-anisidinium cation is adopting a quite planar configuration characterized by a slight r.m.s. deviation of 0.020 (9) Å. Each p-anisidinium cation inter­acts with one [BiI6] octa­hedron via N—HA⋯I3i ( − x, − + y,  − z) , with two water mol­ecules by N—HB⋯OW1ii ( − x, − + y,  − z) and N—HC⋯OW2 hydrogen bonds (Table 2 ▸), as shown in Fig. 4 ▸.

Bottom Line: The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing.The p-anisidinium cations and the water mol-ecules are located in the voids of the anionic sublattice.The cations are linked to each other through N-H⋯O hydrogen bonds with the water mol-ecules, and also through weaker N-H⋯I inter-actions to the anionic inorganic layers.

View Article: PubMed Central - HTML - PubMed

Affiliation: Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, Université de Tunis El Manar, 2092 Manar II Tunis, Tunisia.

ABSTRACT
A new organic-inorganic hybrid material, {(C7H10NO)[BiI4]·2H2O} n , has been synthesized by slow evaporation of an aqueous solution at room temperature. The anionic sublattice of the crystal is built up by [BiI6] octa-hedra sharing edges. The resulting zigzag chains extend along the a-axis direction and are arranged in a distorted hexagonal rod packing. The p-anisidinium cations and the water mol-ecules are located in the voids of the anionic sublattice. The cations are linked to each other through N-H⋯O hydrogen bonds with the water mol-ecules, and also through weaker N-H⋯I inter-actions to the anionic inorganic layers.

No MeSH data available.