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Crystal structure of {6,6'-dihy-droxy-2,2'-[imino-bis-(propane-1,3-diyl-nitrilo-methanylyl-idene)]diphenolato-κ(5) O (1),N,N',N'',O (1')}copper(II).

Noor S, Kumar S, Sabir S, Seidel RW, Goddard R - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent mol-ecules in the asymmetric unit.The Cu(II) atoms are each coordinated by the penta-dentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry.The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms.

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Affiliation: Department of Chemistry, Aligarh Muslim University, Aligarh 202 002, India.

ABSTRACT
The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent mol-ecules in the asymmetric unit. The Cu(II) atoms are each coordinated by the penta-dentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry. The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms. In the crystal, the two independent mol-ecules are each connected into a column along the b axis through inter-molecular O-H⋯O hydrogen bonds. The two independent columns are further linked through an N-H⋯O hydrogen bond, forming a double-column structure.

No MeSH data available.


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Intermolecular O—H···O hydrogen bonds between symmetry-related molecules along the crystallographic b axis.
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Fap2: Intermolecular O—H···O hydrogen bonds between symmetry-related molecules along the crystallographic b axis.


Crystal structure of {6,6'-dihy-droxy-2,2'-[imino-bis-(propane-1,3-diyl-nitrilo-methanylyl-idene)]diphenolato-κ(5) O (1),N,N',N'',O (1')}copper(II).

Noor S, Kumar S, Sabir S, Seidel RW, Goddard R - Acta Crystallogr E Crystallogr Commun (2015)

Intermolecular O—H···O hydrogen bonds between symmetry-related molecules along the crystallographic b axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645064&req=5

Fap2: Intermolecular O—H···O hydrogen bonds between symmetry-related molecules along the crystallographic b axis.
Bottom Line: The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent mol-ecules in the asymmetric unit.The Cu(II) atoms are each coordinated by the penta-dentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry.The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Aligarh Muslim University, Aligarh 202 002, India.

ABSTRACT
The title compound, [Cu(C20H23N3O4)], crystallizes in the space group Cc with two independent mol-ecules in the asymmetric unit. The Cu(II) atoms are each coordinated by the penta-dentate Schiff base ligand in a distorted trigonal bipyramidal N3O2 geometry. The equatorial plane is formed by the two phenolic O atoms and the amine N atom, while the axial positions are occupied by the two imine N atoms. In the crystal, the two independent mol-ecules are each connected into a column along the b axis through inter-molecular O-H⋯O hydrogen bonds. The two independent columns are further linked through an N-H⋯O hydrogen bond, forming a double-column structure.

No MeSH data available.


Related in: MedlinePlus