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Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).

Rojek T, Matczak-Jon E - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations.In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Wrocław University of Technology, 27 Wybrzeże Wyspiańskiego St., 50-370 Wrocław, Poland.

ABSTRACT
In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

No MeSH data available.


Related in: MedlinePlus

A view along the b axis of the crystal packing of the title molecular salt, showing the hydrogen-bonded chains assembled into a layer in the ac plane. Hydrogen bonds are drawn as yellow and light-blue dashed lines (see Table 1). H atoms on C atoms of the cyclohexane rings not involved in hydrogen bonds have been omitted for clarity.
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Fap2: A view along the b axis of the crystal packing of the title molecular salt, showing the hydrogen-bonded chains assembled into a layer in the ac plane. Hydrogen bonds are drawn as yellow and light-blue dashed lines (see Table 1). H atoms on C atoms of the cyclohexane rings not involved in hydrogen bonds have been omitted for clarity.


Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).

Rojek T, Matczak-Jon E - Acta Crystallogr E Crystallogr Commun (2015)

A view along the b axis of the crystal packing of the title molecular salt, showing the hydrogen-bonded chains assembled into a layer in the ac plane. Hydrogen bonds are drawn as yellow and light-blue dashed lines (see Table 1). H atoms on C atoms of the cyclohexane rings not involved in hydrogen bonds have been omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645052&req=5

Fap2: A view along the b axis of the crystal packing of the title molecular salt, showing the hydrogen-bonded chains assembled into a layer in the ac plane. Hydrogen bonds are drawn as yellow and light-blue dashed lines (see Table 1). H atoms on C atoms of the cyclohexane rings not involved in hydrogen bonds have been omitted for clarity.
Bottom Line: In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations.In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Wrocław University of Technology, 27 Wybrzeże Wyspiańskiego St., 50-370 Wrocław, Poland.

ABSTRACT
In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

No MeSH data available.


Related in: MedlinePlus