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Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).

Rojek T, Matczak-Jon E - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations.In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

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Affiliation: Department of Chemistry, Wrocław University of Technology, 27 Wybrzeże Wyspiańskiego St., 50-370 Wrocław, Poland.

ABSTRACT
In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

No MeSH data available.


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The asymmetric unit of the title molecular salt, showing the atom-numbering scheme and the symmetry-independent hydrogen bonds (orange and light-blue dashed lines; see Table 1). Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: The asymmetric unit of the title molecular salt, showing the atom-numbering scheme and the symmetry-independent hydrogen bonds (orange and light-blue dashed lines; see Table 1). Displacement ellipsoids are drawn at the 50% probability level.


Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).

Rojek T, Matczak-Jon E - Acta Crystallogr E Crystallogr Commun (2015)

The asymmetric unit of the title molecular salt, showing the atom-numbering scheme and the symmetry-independent hydrogen bonds (orange and light-blue dashed lines; see Table 1). Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645052&req=5

Fap1: The asymmetric unit of the title molecular salt, showing the atom-numbering scheme and the symmetry-independent hydrogen bonds (orange and light-blue dashed lines; see Table 1). Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations.In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Wrocław University of Technology, 27 Wybrzeże Wyspiańskiego St., 50-370 Wrocław, Poland.

ABSTRACT
In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.

No MeSH data available.


Related in: MedlinePlus