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Crystal structure of tris-(hydroxyl-ammonium) orthophosphate.

Leinemann M, Jess I, Boeckmann J, Näther C - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The atoms of the cation occupy general positions, whereas the anion is located on a threefold rotation axis that runs through the phospho-rus atom and one of the phosphate O atoms.In the crystal structure, cations and anions are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.Altogether, one very strong O-H⋯O, two N-H⋯O hydrogen bonds of medium strength and two weaker bifurcated N-H⋯O inter-actions are observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Dräger Safety AG & Co. KGaA, Revalstrasse 1, 23560 Lübeck, Germany.

ABSTRACT
The crystal structure of the title salt, ([H3NOH](+))3·[PO4](3-), consists of discrete hydroxyl-ammonium cations and ortho-phos-phate anions. The atoms of the cation occupy general positions, whereas the anion is located on a threefold rotation axis that runs through the phospho-rus atom and one of the phosphate O atoms. In the crystal structure, cations and anions are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network. Altogether, one very strong O-H⋯O, two N-H⋯O hydrogen bonds of medium strength and two weaker bifurcated N-H⋯O inter-actions are observed.

No MeSH data available.


Related in: MedlinePlus

View of the molecular components of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. [Symmetry codes: i) = -x+y, -x+1, z, ii) = -y+1, x-y, z.]
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Fap1: View of the molecular components of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. [Symmetry codes: i) = -x+y, -x+1, z, ii) = -y+1, x-y, z.]


Crystal structure of tris-(hydroxyl-ammonium) orthophosphate.

Leinemann M, Jess I, Boeckmann J, Näther C - Acta Crystallogr E Crystallogr Commun (2015)

View of the molecular components of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. [Symmetry codes: i) = -x+y, -x+1, z, ii) = -y+1, x-y, z.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645030&req=5

Fap1: View of the molecular components of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level. [Symmetry codes: i) = -x+y, -x+1, z, ii) = -y+1, x-y, z.]
Bottom Line: The atoms of the cation occupy general positions, whereas the anion is located on a threefold rotation axis that runs through the phospho-rus atom and one of the phosphate O atoms.In the crystal structure, cations and anions are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network.Altogether, one very strong O-H⋯O, two N-H⋯O hydrogen bonds of medium strength and two weaker bifurcated N-H⋯O inter-actions are observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Dräger Safety AG & Co. KGaA, Revalstrasse 1, 23560 Lübeck, Germany.

ABSTRACT
The crystal structure of the title salt, ([H3NOH](+))3·[PO4](3-), consists of discrete hydroxyl-ammonium cations and ortho-phos-phate anions. The atoms of the cation occupy general positions, whereas the anion is located on a threefold rotation axis that runs through the phospho-rus atom and one of the phosphate O atoms. In the crystal structure, cations and anions are linked by inter-molecular O-H⋯O and N-H⋯O hydrogen bonds into a three-dimensional network. Altogether, one very strong O-H⋯O, two N-H⋯O hydrogen bonds of medium strength and two weaker bifurcated N-H⋯O inter-actions are observed.

No MeSH data available.


Related in: MedlinePlus