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Crystal structure of 5-(5-chloro-2-hydroxy-benzo-yl)-2-(2-methyl-1H-indol-3-yl)nicotino-nitrile.

Vimala G, Poomathi N, AaminaNaaz Y, Perumal PT, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title compound, C22H14ClN3O2, the indole unit is essentially coplanar, with a maximum deviation of 0.035 Å for the C atom bearing the methyl group.The central pyridine ring is inclined to the indole ring system by 43.7 (1)°.The dihedral angle between the phenyl ring and the indole ring system is 15.7 (2)°, while that between the phenyl ring and the central pyridine ring is 46.3 (1)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.

ABSTRACT
In the title compound, C22H14ClN3O2, the indole unit is essentially coplanar, with a maximum deviation of 0.035 Å for the C atom bearing the methyl group. The central pyridine ring is inclined to the indole ring system by 43.7 (1)°. The dihedral angle between the phenyl ring and the indole ring system is 15.7 (2)°, while that between the phenyl ring and the central pyridine ring is 46.3 (1)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯O hydrogen bonding, forming an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers with an R 2 (2)(16) ring motif. The crystal structure also features C-H⋯π and π-π inter-actions [centroid-centroid separation = 3.688 (1) Å].

No MeSH data available.


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O—H···O intra and N—H···N intermlecular interactions (dotted lines) in the crystal structure of the title compound. The crystal packing of the molecules is viewed down the b axis.
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Fap2: O—H···O intra and N—H···N intermlecular interactions (dotted lines) in the crystal structure of the title compound. The crystal packing of the molecules is viewed down the b axis.


Crystal structure of 5-(5-chloro-2-hydroxy-benzo-yl)-2-(2-methyl-1H-indol-3-yl)nicotino-nitrile.

Vimala G, Poomathi N, AaminaNaaz Y, Perumal PT, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

O—H···O intra and N—H···N intermlecular interactions (dotted lines) in the crystal structure of the title compound. The crystal packing of the molecules is viewed down the b axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4645016&req=5

Fap2: O—H···O intra and N—H···N intermlecular interactions (dotted lines) in the crystal structure of the title compound. The crystal packing of the molecules is viewed down the b axis.
Bottom Line: In the title compound, C22H14ClN3O2, the indole unit is essentially coplanar, with a maximum deviation of 0.035 Å for the C atom bearing the methyl group.The central pyridine ring is inclined to the indole ring system by 43.7 (1)°.The dihedral angle between the phenyl ring and the indole ring system is 15.7 (2)°, while that between the phenyl ring and the central pyridine ring is 46.3 (1)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.

ABSTRACT
In the title compound, C22H14ClN3O2, the indole unit is essentially coplanar, with a maximum deviation of 0.035 Å for the C atom bearing the methyl group. The central pyridine ring is inclined to the indole ring system by 43.7 (1)°. The dihedral angle between the phenyl ring and the indole ring system is 15.7 (2)°, while that between the phenyl ring and the central pyridine ring is 46.3 (1)°. The mol-ecular structure is stabilized by an intra-molecular O-H⋯O hydrogen bonding, forming an S(6) ring motif. In the crystal, mol-ecules are linked via pairs of N-H⋯N hydrogen bonds, forming inversion dimers with an R 2 (2)(16) ring motif. The crystal structure also features C-H⋯π and π-π inter-actions [centroid-centroid separation = 3.688 (1) Å].

No MeSH data available.


Related in: MedlinePlus