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Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

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bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

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(a) Structureof nanopore gate, and (b) controlled release of guestfrom nanopores.1664 Reprinted with permissionfrom ref (14). Copyright2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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fig66: (a) Structureof nanopore gate, and (b) controlled release of guestfrom nanopores.1664 Reprinted with permissionfrom ref (14). Copyright2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mentions: Interlocked architectures such as bistable rotaxane 158 have been used to restrict or allow access to the poresin materials such as mesoporous silica particles.1664 The positively charged macrocyclic ring initially prefersthe TTF station, and in this conformation, diffusion into and outof the nanopores of the silica is allowed. Oxidation of the TTF moietycauses shuttling of the ring to the dioxynaphthalene station, andclosure of the nanopores, trapping a portion of the solvent/solutemixture. Solvent exchange and reduction of the oxidized TTF stationleads to guest release (Figure 66). The aggregation and deaggregation of a polymericmaterial has been caused by the formation of pseudorotaxanes betweenstrands. This has been used to transiently trap nanoparticles in thepores formed upon aggregation.1665


Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

(a) Structureof nanopore gate, and (b) controlled release of guestfrom nanopores.1664 Reprinted with permissionfrom ref (14). Copyright2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
© Copyright Policy
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4585175&req=5

fig66: (a) Structureof nanopore gate, and (b) controlled release of guestfrom nanopores.1664 Reprinted with permissionfrom ref (14). Copyright2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Mentions: Interlocked architectures such as bistable rotaxane 158 have been used to restrict or allow access to the poresin materials such as mesoporous silica particles.1664 The positively charged macrocyclic ring initially prefersthe TTF station, and in this conformation, diffusion into and outof the nanopores of the silica is allowed. Oxidation of the TTF moietycauses shuttling of the ring to the dioxynaphthalene station, andclosure of the nanopores, trapping a portion of the solvent/solutemixture. Solvent exchange and reduction of the oxidized TTF stationleads to guest release (Figure 66). The aggregation and deaggregation of a polymericmaterial has been caused by the formation of pseudorotaxanes betweenstrands. This has been used to transiently trap nanoparticles in thepores formed upon aggregation.1665

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

No MeSH data available.