Limits...
Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

No MeSH data available.


One enantiomerof chiral molecule 94, in which directionalrotational motion was driven by linearly polarized laser pulses andstudied by quantum and classical mechanical simulations.940
© Copyright Policy
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4585175&req=5

fig34: One enantiomerof chiral molecule 94, in which directionalrotational motion was driven by linearly polarized laser pulses andstudied by quantum and classical mechanical simulations.940

Mentions: Fujimura and co-workers undertook a series of theoreticalstudiesinto the mechanism of rotation in gas-phase directional chiral motorsdriven by picosecond pulses of a linearly polarized laser.938−950 In one study, aldehyde 94 was examined as a chiralmolecular motor with the formyl group as the rotor (Figure 34). They considered both enantiomersin their studies and came to the conclusion that directional motionoriginated from the asymmetric potential-energy surface of the chiralmolecules and time-correlated forces created by laser-permanent dipoleinteractions.940 The process is reminiscentof a rocking Brownian ratchet (section 1.6.2), but here thermal energy is not requiredto surmount kinetic barriers.951


Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

One enantiomerof chiral molecule 94, in which directionalrotational motion was driven by linearly polarized laser pulses andstudied by quantum and classical mechanical simulations.940
© Copyright Policy
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4585175&req=5

fig34: One enantiomerof chiral molecule 94, in which directionalrotational motion was driven by linearly polarized laser pulses andstudied by quantum and classical mechanical simulations.940
Mentions: Fujimura and co-workers undertook a series of theoreticalstudiesinto the mechanism of rotation in gas-phase directional chiral motorsdriven by picosecond pulses of a linearly polarized laser.938−950 In one study, aldehyde 94 was examined as a chiralmolecular motor with the formyl group as the rotor (Figure 34). They considered both enantiomersin their studies and came to the conclusion that directional motionoriginated from the asymmetric potential-energy surface of the chiralmolecules and time-correlated forces created by laser-permanent dipoleinteractions.940 The process is reminiscentof a rocking Brownian ratchet (section 1.6.2), but here thermal energy is not requiredto surmount kinetic barriers.951

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

No MeSH data available.