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Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

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Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

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bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

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Cerium(IV) bis(porphyrinate) double decker (top unit)and a rhodium(III)porphyrin-based side cog. The two units are connected through a coordinationbond between rhodium(III) and a pyridyl group.249
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fig14: Cerium(IV) bis(porphyrinate) double decker (top unit)and a rhodium(III)porphyrin-based side cog. The two units are connected through a coordinationbond between rhodium(III) and a pyridyl group.249

Mentions: Ever more complicated systems such as multidecker pophyrin complexes246 and mechanically interlocked porphyrin systemslike 18 have been synthesized (Figure 14).247−249 The latter consist of cerium(IV)or lanthanum(III) bis(porphyrinate) double decker complexes and oneor two orthogonal porphyrin molecules. In these “moleculargears”, the rotation of the top and side units could be partiallycoupled through mechanical interactions between the different units.A folding ruler based on similar principles has been reported.250 A dodecanuclear four level complex that mimicsa double ball bearing has also been synthesized.251


Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

Cerium(IV) bis(porphyrinate) double decker (top unit)and a rhodium(III)porphyrin-based side cog. The two units are connected through a coordinationbond between rhodium(III) and a pyridyl group.249
© Copyright Policy
Related In: Results  -  Collection

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Show All Figures
getmorefigures.php?uid=PMC4585175&req=5

fig14: Cerium(IV) bis(porphyrinate) double decker (top unit)and a rhodium(III)porphyrin-based side cog. The two units are connected through a coordinationbond between rhodium(III) and a pyridyl group.249
Mentions: Ever more complicated systems such as multidecker pophyrin complexes246 and mechanically interlocked porphyrin systemslike 18 have been synthesized (Figure 14).247−249 The latter consist of cerium(IV)or lanthanum(III) bis(porphyrinate) double decker complexes and oneor two orthogonal porphyrin molecules. In these “moleculargears”, the rotation of the top and side units could be partiallycoupled through mechanical interactions between the different units.A folding ruler based on similar principles has been reported.250 A dodecanuclear four level complex that mimicsa double ball bearing has also been synthesized.251

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

No MeSH data available.