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Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

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bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

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Minimization of Steric Interactions between Aromatic Groupsand SubstituentResults in (P,P)-(trans)-41-Stable Ground-State Conformation, with Axial Substituents(i) Photochemical isomerizationleaves substituents in the unstable equatorial conformation (M,M)-(cis)-41-unstable. (ii) Steric strain is released by a thermally activatedhelicity inversion leading to (P,P)-(cis)-41-stable. (iii) Photoisomerizationfrom cis to trans. (iv) Helicalinversion completes a full rotation.429
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sch13: Minimization of Steric Interactions between Aromatic Groupsand SubstituentResults in (P,P)-(trans)-41-Stable Ground-State Conformation, with Axial Substituents(i) Photochemical isomerizationleaves substituents in the unstable equatorial conformation (M,M)-(cis)-41-unstable. (ii) Steric strain is released by a thermally activatedhelicity inversion leading to (P,P)-(cis)-41-stable. (iii) Photoisomerizationfrom cis to trans. (iv) Helicalinversion completes a full rotation.429


Artificial Molecular Machines.

Erbas-Cakmak S, Leigh DA, McTernan CT, Nussbaumer AL - Chem. Rev. (2015)

Minimization of Steric Interactions between Aromatic Groupsand SubstituentResults in (P,P)-(trans)-41-Stable Ground-State Conformation, with Axial Substituents(i) Photochemical isomerizationleaves substituents in the unstable equatorial conformation (M,M)-(cis)-41-unstable. (ii) Steric strain is released by a thermally activatedhelicity inversion leading to (P,P)-(cis)-41-stable. (iii) Photoisomerizationfrom cis to trans. (iv) Helicalinversion completes a full rotation.429
© Copyright Policy
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4585175&req=5

sch13: Minimization of Steric Interactions between Aromatic Groupsand SubstituentResults in (P,P)-(trans)-41-Stable Ground-State Conformation, with Axial Substituents(i) Photochemical isomerizationleaves substituents in the unstable equatorial conformation (M,M)-(cis)-41-unstable. (ii) Steric strain is released by a thermally activatedhelicity inversion leading to (P,P)-(cis)-41-stable. (iii) Photoisomerizationfrom cis to trans. (iv) Helicalinversion completes a full rotation.429

View Article: PubMed Central - PubMed

Affiliation: School of Chemistry, University of Manchester , Oxford Road, Manchester M13 9PL, United Kingdom.

AUTOMATICALLY GENERATED EXCERPT
Please rate it.

bonded molecules and on catenanes and rotaxanes in which switching of other protic solvents... This effect (listed in descending binding ability) stations on the thread, macrocycle In these systems, fast-responding reporters are preferred... practical applications by utilizing molecular scale changes to create macroscopic effects... The thread of these rotaxanes included an anthracene fluorophore similar application in synthetic polymers often furnishes a useful result... of Brownian motion can be exploited to great effect in the synthesis every aspect of functional molecule and materials design... An improved robotics” in which ratcheted motions of molecular components

No MeSH data available.


Related in: MedlinePlus