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Crystal structure of bis-[μ-1,2-bis-(di-phenyl-phosphan-yl)ethane-κ(2) P:P']bis[(N,N'-di-ethyl-thio-urea-κS)iodidocopper(I)].

Khongsichan L, Nimthong-Roldán A, Pakawatchai C, Wongnawa S - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre.The Cu(I) atom displays a distorted tetra-hedral coordination geometry defined by one S atom of an N,N'-di-ethyl-thio-urea ligand, two P atoms derived from two bridging 1,2-bis-(di-phenyl-phosphan-yl)ethane (dppe) ligands and one iodide ion.The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu2P4C4 ring.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.

ABSTRACT
The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre. The Cu(I) atom displays a distorted tetra-hedral coordination geometry defined by one S atom of an N,N'-di-ethyl-thio-urea ligand, two P atoms derived from two bridging 1,2-bis-(di-phenyl-phosphan-yl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu2P4C4 ring. An intra-molecular N-H⋯I hydrogen bond is noted. In the crystal, N-H⋯I hydrogen bonds link complex mol-ecules into layers parallel to (-101).

No MeSH data available.


Part of the crystal structure showing intra/inter-molecular N—H···I hydrogen bonds forming a layers as dashed lines.
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Fap2: Part of the crystal structure showing intra/inter-molecular N—H···I hydrogen bonds forming a layers as dashed lines.


Crystal structure of bis-[μ-1,2-bis-(di-phenyl-phosphan-yl)ethane-κ(2) P:P']bis[(N,N'-di-ethyl-thio-urea-κS)iodidocopper(I)].

Khongsichan L, Nimthong-Roldán A, Pakawatchai C, Wongnawa S - Acta Crystallogr E Crystallogr Commun (2015)

Part of the crystal structure showing intra/inter-molecular N—H···I hydrogen bonds forming a layers as dashed lines.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4555430&req=5

Fap2: Part of the crystal structure showing intra/inter-molecular N—H···I hydrogen bonds forming a layers as dashed lines.
Bottom Line: The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre.The Cu(I) atom displays a distorted tetra-hedral coordination geometry defined by one S atom of an N,N'-di-ethyl-thio-urea ligand, two P atoms derived from two bridging 1,2-bis-(di-phenyl-phosphan-yl)ethane (dppe) ligands and one iodide ion.The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu2P4C4 ring.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.

ABSTRACT
The binuclear title complex, [Cu2I2(C26H24P2)2(C5H12N2S)2], lies about an inversion centre. The Cu(I) atom displays a distorted tetra-hedral coordination geometry defined by one S atom of an N,N'-di-ethyl-thio-urea ligand, two P atoms derived from two bridging 1,2-bis-(di-phenyl-phosphan-yl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu2P4C4 ring. An intra-molecular N-H⋯I hydrogen bond is noted. In the crystal, N-H⋯I hydrogen bonds link complex mol-ecules into layers parallel to (-101).

No MeSH data available.