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Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).

Kondrashov M, Fleckhaus A, Gritcenko R, Wendt OF - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity.The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°.Mol-ecules pack via dispersion inter-actions.

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Affiliation: Centre for Analysis and Synthesis, Department of Chemistry, Lund University, PO Box 124, S-221 00 Lund, Sweden.

ABSTRACT
The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.

No MeSH data available.


The molecular structure of one of the molecules in the asymmetric unit with atom labels and 50% probability displacement ellipsoids. H-atoms are omitted for clarity.
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Fap1: The molecular structure of one of the molecules in the asymmetric unit with atom labels and 50% probability displacement ellipsoids. H-atoms are omitted for clarity.


Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).

Kondrashov M, Fleckhaus A, Gritcenko R, Wendt OF - Acta Crystallogr E Crystallogr Commun (2015)

The molecular structure of one of the molecules in the asymmetric unit with atom labels and 50% probability displacement ellipsoids. H-atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4555382&req=5

Fap1: The molecular structure of one of the molecules in the asymmetric unit with atom labels and 50% probability displacement ellipsoids. H-atoms are omitted for clarity.
Bottom Line: The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity.The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°.Mol-ecules pack via dispersion inter-actions.

View Article: PubMed Central - HTML - PubMed

Affiliation: Centre for Analysis and Synthesis, Department of Chemistry, Lund University, PO Box 124, S-221 00 Lund, Sweden.

ABSTRACT
The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.

No MeSH data available.