Limits...
Effect of Temperature on the Aging rate of Li Ion Battery Operating above Room Temperature.

Leng F, Tan CM, Pecht M - Sci Rep (2015)

Bottom Line: However, the comprehensive effects of temperature on the cyclic aging rate of LiB have yet to be found.In particular, the formation and modification of the surface films on the electrodes as well as structural/phase changes of the LCO electrode, as reported in the literatures, are found to be the main contributors to the increasing degradation rate of the maximum charge storage of LiB with temperature for the specific operating temperature range.Larger increases in the Warburg elements and cell impedance are also found with cycling at higher temperature, but they do not seriously affect the state of health (SoH) of LiB as shown in this work.

View Article: PubMed Central - PubMed

Affiliation: 1] Nanyang Technological University, School of Electrical Electronics Engineering, Blk S2.1, 50 Nanyang Avenue, Singapore 639798, Singapore [2] TUM CREATE PTE LTD, 1 Create Way, #10-02 Create Tower, Singapore 138602, Singapore [3] Global Energy Quality And Reliability Technology (G.E.Q.A.R.T). PTE.LTD, Sims Residence, 8 Lorong, 29 Geylang #06-12, Singapore 387882, Singapore.

ABSTRACT
Temperature is known to have a significant impact on the performance, safety, and cycle lifetime of lithium-ion batteries (LiB). However, the comprehensive effects of temperature on the cyclic aging rate of LiB have yet to be found. We use an electrochemistry-based model (ECBE) here to measure the effects on the aging behavior of cycled LiB operating within the temperature range of 25 °C to 55 °C. The increasing degradation rate of the maximum charge storage of LiB during cycling at elevated temperature is found to relate mainly to the degradations at the electrodes, and that the degradation of LCO cathode is larger than graphite anode at elevated temperature. In particular, the formation and modification of the surface films on the electrodes as well as structural/phase changes of the LCO electrode, as reported in the literatures, are found to be the main contributors to the increasing degradation rate of the maximum charge storage of LiB with temperature for the specific operating temperature range. Larger increases in the Warburg elements and cell impedance are also found with cycling at higher temperature, but they do not seriously affect the state of health (SoH) of LiB as shown in this work.

No MeSH data available.


Related in: MedlinePlus

Electrochemistry-based electrical model11.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4526891&req=5

f4: Electrochemistry-based electrical model11.

Mentions: Figure 4 shows the ECBE model, where Re is the combined ohmic resistance of the electrodes and the electrode/electrolyte interface, Cdl is the double layer capacitance, Rct is the total charge transfer resistances at the electrodes, K is the charge transfer rate constant at the electrodes embedded in the Butler-Volmer impedance (ZBV), and Rn and Cw are the Warburg element in the electrolyte.


Effect of Temperature on the Aging rate of Li Ion Battery Operating above Room Temperature.

Leng F, Tan CM, Pecht M - Sci Rep (2015)

Electrochemistry-based electrical model11.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4526891&req=5

f4: Electrochemistry-based electrical model11.
Mentions: Figure 4 shows the ECBE model, where Re is the combined ohmic resistance of the electrodes and the electrode/electrolyte interface, Cdl is the double layer capacitance, Rct is the total charge transfer resistances at the electrodes, K is the charge transfer rate constant at the electrodes embedded in the Butler-Volmer impedance (ZBV), and Rn and Cw are the Warburg element in the electrolyte.

Bottom Line: However, the comprehensive effects of temperature on the cyclic aging rate of LiB have yet to be found.In particular, the formation and modification of the surface films on the electrodes as well as structural/phase changes of the LCO electrode, as reported in the literatures, are found to be the main contributors to the increasing degradation rate of the maximum charge storage of LiB with temperature for the specific operating temperature range.Larger increases in the Warburg elements and cell impedance are also found with cycling at higher temperature, but they do not seriously affect the state of health (SoH) of LiB as shown in this work.

View Article: PubMed Central - PubMed

Affiliation: 1] Nanyang Technological University, School of Electrical Electronics Engineering, Blk S2.1, 50 Nanyang Avenue, Singapore 639798, Singapore [2] TUM CREATE PTE LTD, 1 Create Way, #10-02 Create Tower, Singapore 138602, Singapore [3] Global Energy Quality And Reliability Technology (G.E.Q.A.R.T). PTE.LTD, Sims Residence, 8 Lorong, 29 Geylang #06-12, Singapore 387882, Singapore.

ABSTRACT
Temperature is known to have a significant impact on the performance, safety, and cycle lifetime of lithium-ion batteries (LiB). However, the comprehensive effects of temperature on the cyclic aging rate of LiB have yet to be found. We use an electrochemistry-based model (ECBE) here to measure the effects on the aging behavior of cycled LiB operating within the temperature range of 25 °C to 55 °C. The increasing degradation rate of the maximum charge storage of LiB during cycling at elevated temperature is found to relate mainly to the degradations at the electrodes, and that the degradation of LCO cathode is larger than graphite anode at elevated temperature. In particular, the formation and modification of the surface films on the electrodes as well as structural/phase changes of the LCO electrode, as reported in the literatures, are found to be the main contributors to the increasing degradation rate of the maximum charge storage of LiB with temperature for the specific operating temperature range. Larger increases in the Warburg elements and cell impedance are also found with cycling at higher temperature, but they do not seriously affect the state of health (SoH) of LiB as shown in this work.

No MeSH data available.


Related in: MedlinePlus