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A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide.

Czakler M, Puchberger M, Artner C, Schubert U - Monatsh. Chem. (2014)

Bottom Line: The coordination polymer [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)] n was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide.The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)3 groups through OR bridges was observed.

View Article: PubMed Central - PubMed

Affiliation: Institute of Materials Chemistry, Vienna University of Technology, Vienna, Austria.

ABSTRACT

Abstract: The coordination polymer [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)] n was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)3 groups through OR bridges was observed.

No MeSH data available.


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Mentions: [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)]n (1) was obtained by reaction of Ti(OiPr)4 with an equimolar amount of 4-(imidazol-1-yl)butyric acid (L–H) in isopropanol (Scheme 1).


A coordination polymer with unusual structural features from imidazolylbutyric acid and titanium isopropoxide.

Czakler M, Puchberger M, Artner C, Schubert U - Monatsh. Chem. (2014)

© Copyright Policy - OpenAccess
Related In: Results  -  Collection

Show All Figures
getmorefigures.php?uid=PMC4494772&req=5

Mentions: [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)]n (1) was obtained by reaction of Ti(OiPr)4 with an equimolar amount of 4-(imidazol-1-yl)butyric acid (L–H) in isopropanol (Scheme 1).

Bottom Line: The coordination polymer [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)] n was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide.The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)3 groups through OR bridges was observed.

View Article: PubMed Central - PubMed

Affiliation: Institute of Materials Chemistry, Vienna University of Technology, Vienna, Austria.

ABSTRACT

Abstract: The coordination polymer [Ti(OiPr)3(OOCCH2CH2CH2C3N2H3)] n was prepared from 4-(imidazol-1-yl)butyric acid and titanium isopropoxide. The structure of the compound is remarkable, as the carboxylate group is coordinated in a chelating manner and no dimerization of the Ti(OiPr)3 groups through OR bridges was observed.

No MeSH data available.