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A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization.

Gutekunst WR, Hawker CJ - J. Am. Chem. Soc. (2015)

Bottom Line: A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures.Central to this approach is the development of a small molecule "polymerization trigger" which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.

View Article: PubMed Central - PubMed

Affiliation: †Materials Department, Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States.

ABSTRACT
A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule "polymerization trigger" which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.

No MeSH data available.


Synthesis and X-ray Crystal Structureof Macrocyclic Monomer 9
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A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization.

Gutekunst WR, Hawker CJ - J. Am. Chem. Soc. (2015)

Synthesis and X-ray Crystal Structureof Macrocyclic Monomer 9
© Copyright Policy - editor-choice
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4490773&req=5

sch3: Synthesis and X-ray Crystal Structureof Macrocyclic Monomer 9
Bottom Line: A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures.Central to this approach is the development of a small molecule "polymerization trigger" which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.

View Article: PubMed Central - PubMed

Affiliation: †Materials Department, Materials Research Laboratory, University of California, Santa Barbara, California 93106, United States.

ABSTRACT
A new and general strategy for the synthesis of sequence-defined polymers is described that employs relay metathesis to promote the ring opening polymerization of unstrained macrocyclic structures. Central to this approach is the development of a small molecule "polymerization trigger" which when coupled with a diverse range of sequence-defined units allows for the controlled, directional synthesis of sequence controlled polymers.

No MeSH data available.