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Crystal structure of 4-[1-(2-hy-droxy-prop-yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid.

Jasinski JP, Mohamed SK, Akkurt M, Abdelhamid AA, Albayati MR - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title compound, C25H22N2O3, the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively.The phenyl ring adjacent to the N-bonded 2-hy-droxy-propyl group shows the greatest twist, presumably to minimize steric inter-actions.In addition, C-H⋯π inter-actions are also observed.

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Affiliation: Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.

ABSTRACT
In the title compound, C25H22N2O3, the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy-droxy-propyl group shows the greatest twist, presumably to minimize steric inter-actions. In the crystal, mol-ecules are linked by O-H⋯N, O-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C-H⋯π inter-actions are also observed.

No MeSH data available.


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View of a part of the hydrogen bonding in the title compound
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Fap2: View of a part of the hydrogen bonding in the title compound


Crystal structure of 4-[1-(2-hy-droxy-prop-yl)-4,5-diphenyl-1H-imidazol-2-yl]benzoic acid.

Jasinski JP, Mohamed SK, Akkurt M, Abdelhamid AA, Albayati MR - Acta Crystallogr E Crystallogr Commun (2015)

View of a part of the hydrogen bonding in the title compound
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384621&req=5

Fap2: View of a part of the hydrogen bonding in the title compound
Bottom Line: In the title compound, C25H22N2O3, the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively.The phenyl ring adjacent to the N-bonded 2-hy-droxy-propyl group shows the greatest twist, presumably to minimize steric inter-actions.In addition, C-H⋯π inter-actions are also observed.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA.

ABSTRACT
In the title compound, C25H22N2O3, the central imidazole ring makes dihedral angles of 48.43 (10), 20.23 (10) and 75.38 (11)° with the benzene ring and the two phenyl rings, respectively. The phenyl ring adjacent to the N-bonded 2-hy-droxy-propyl group shows the greatest twist, presumably to minimize steric inter-actions. In the crystal, mol-ecules are linked by O-H⋯N, O-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network. In addition, C-H⋯π inter-actions are also observed.

No MeSH data available.


Related in: MedlinePlus