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Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Nawaz S, Tahir MN, Nadeem MA, Mehmood B, Ahmad S - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°.The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°.In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

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Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

No MeSH data available.


A partial packing diagram (PLATON; Spek, 2009 ▸) illustrating the formation of sheets of mol­ecules with various loops via hydrogen-bonding inter­actions (shown as dashed lines).
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fig2: A partial packing diagram (PLATON; Spek, 2009 ▸) illustrating the formation of sheets of mol­ecules with various loops via hydrogen-bonding inter­actions (shown as dashed lines).

Mentions: In the asymmetric unit, strong N—H⋯S, N—H⋯O hydrogen bonds complete distorted S(6) and (8) loops. The other hydrogen-bonding inter­actions are of the C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S types (Table 2 ▸, Fig. 2 ▸) and lead to a two-dimensional polymeric network in the (10) plane.


Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Nawaz S, Tahir MN, Nadeem MA, Mehmood B, Ahmad S - Acta Crystallogr E Crystallogr Commun (2015)

A partial packing diagram (PLATON; Spek, 2009 ▸) illustrating the formation of sheets of mol­ecules with various loops via hydrogen-bonding inter­actions (shown as dashed lines).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384606&req=5

fig2: A partial packing diagram (PLATON; Spek, 2009 ▸) illustrating the formation of sheets of mol­ecules with various loops via hydrogen-bonding inter­actions (shown as dashed lines).
Mentions: In the asymmetric unit, strong N—H⋯S, N—H⋯O hydrogen bonds complete distorted S(6) and (8) loops. The other hydrogen-bonding inter­actions are of the C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S types (Table 2 ▸, Fig. 2 ▸) and lead to a two-dimensional polymeric network in the (10) plane.

Bottom Line: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°.The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°.In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

No MeSH data available.