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Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Nawaz S, Tahir MN, Nadeem MA, Mehmood B, Ahmad S - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°.The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°.In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

No MeSH data available.


View of the title compound with displacement ellipsoids drawn at the 50% probability level.
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fig1: View of the title compound with displacement ellipsoids drawn at the 50% probability level.

Mentions: Silver(I) forms relatively stable compounds with phosphanes and sulfur donor thione ligands due to favorable soft acid–soft base inter­actions (Ferrari et al., 2007 ▸; Isab et al. 2010 ▸; Karagiannidis et al., 1990 ▸; Nawaz et al., 2011 ▸; Rüffer et al., 2011 ▸). Inter­est in these complexes arises from their luminescent (Ferrari et al., 2007 ▸), anti­microbial (Ruan et al., 2009 ▸) and anti­tumor properties (Liu et al., 2008 ▸). In the light of this, the crystal structures of several silver(I) complexes of phosphanes and thio­nes have been reported in the literature (Ferrari et al., 2007 ▸; Isab et al., 2010 ▸; Karagiannidis et al., 1990 ▸; Nawaz et al., 2011 ▸; Rüffer et al., 2011 ▸). Here, we report the crystal structure of a new silver(I) complex of tri­phenyl­phosphane (PPh3) and thio­urea (tu), (I) (Fig. 1 ▸).


Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Nawaz S, Tahir MN, Nadeem MA, Mehmood B, Ahmad S - Acta Crystallogr E Crystallogr Commun (2015)

View of the title compound with displacement ellipsoids drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384606&req=5

fig1: View of the title compound with displacement ellipsoids drawn at the 50% probability level.
Mentions: Silver(I) forms relatively stable compounds with phosphanes and sulfur donor thione ligands due to favorable soft acid–soft base inter­actions (Ferrari et al., 2007 ▸; Isab et al. 2010 ▸; Karagiannidis et al., 1990 ▸; Nawaz et al., 2011 ▸; Rüffer et al., 2011 ▸). Inter­est in these complexes arises from their luminescent (Ferrari et al., 2007 ▸), anti­microbial (Ruan et al., 2009 ▸) and anti­tumor properties (Liu et al., 2008 ▸). In the light of this, the crystal structures of several silver(I) complexes of phosphanes and thio­nes have been reported in the literature (Ferrari et al., 2007 ▸; Isab et al., 2010 ▸; Karagiannidis et al., 1990 ▸; Nawaz et al., 2011 ▸; Rüffer et al., 2011 ▸). Here, we report the crystal structure of a new silver(I) complex of tri­phenyl­phosphane (PPh3) and thio­urea (tu), (I) (Fig. 1 ▸).

Bottom Line: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°.The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°.In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.

ABSTRACT
In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.

No MeSH data available.