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Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]nickel(II).

Howlader MB, Begum MS, Sheikh MC, Miyatake R, Zangrando E - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands.In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.

ABSTRACT
In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.

No MeSH data available.


Related in: MedlinePlus

ORTEP drawing (ellipsoid probability at 50%) of the centrosymmetric NiL2 complex.
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Fap1: ORTEP drawing (ellipsoid probability at 50%) of the centrosymmetric NiL2 complex.


Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]nickel(II).

Howlader MB, Begum MS, Sheikh MC, Miyatake R, Zangrando E - Acta Crystallogr E Crystallogr Commun (2015)

ORTEP drawing (ellipsoid probability at 50%) of the centrosymmetric NiL2 complex.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384570&req=5

Fap1: ORTEP drawing (ellipsoid probability at 50%) of the centrosymmetric NiL2 complex.
Bottom Line: In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands.In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.

ABSTRACT
In the title complex, [Ni(C15H21N2S2)2], the Ni(II) atom exhibits a square-planar coordination geometry and is located on an inversion centre leading to a trans configuration of the N,S-chelating ligands. In the crystal, the complex mol-ecules stack at a distance of 4.6738 (3) Å along the a axis, which exclude any significant inter-actions between the aromatic rings.

No MeSH data available.


Related in: MedlinePlus