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Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

Govindaraj J, Thirumurugan S, Reddy DS, Anbalagan K, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron.The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio.C-H⋯Cl inter-actions also occur.

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Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into sheets perpendicular to the a axis. C-H⋯Cl inter-actions also occur.

No MeSH data available.


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The crystal packing of the title compound viewed down the a axis showing the hydrogen bonded sheet. Hydrogen bond are shown as dashed lines. The minor disorder component and hydrogen atoms not participating in N—H···Cl interactions are omitted for clarity.
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Fap2: The crystal packing of the title compound viewed down the a axis showing the hydrogen bonded sheet. Hydrogen bond are shown as dashed lines. The minor disorder component and hydrogen atoms not participating in N—H···Cl interactions are omitted for clarity.


Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

Govindaraj J, Thirumurugan S, Reddy DS, Anbalagan K, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

The crystal packing of the title compound viewed down the a axis showing the hydrogen bonded sheet. Hydrogen bond are shown as dashed lines. The minor disorder component and hydrogen atoms not participating in N—H···Cl interactions are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
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getmorefigures.php?uid=PMC4384566&req=5

Fap2: The crystal packing of the title compound viewed down the a axis showing the hydrogen bonded sheet. Hydrogen bond are shown as dashed lines. The minor disorder component and hydrogen atoms not participating in N—H···Cl interactions are omitted for clarity.
Bottom Line: The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron.The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio.C-H⋯Cl inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into sheets perpendicular to the a axis. C-H⋯Cl inter-actions also occur.

No MeSH data available.


Related in: MedlinePlus