Limits...
Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

Govindaraj J, Thirumurugan S, Reddy DS, Anbalagan K, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron.The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio.C-H⋯Cl inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into sheets perpendicular to the a axis. C-H⋯Cl inter-actions also occur.

No MeSH data available.


Related in: MedlinePlus

The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4384566&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level.


Crystal structure of di-chlorido-bis-(4-ethyl-aniline-κN)zinc.

Govindaraj J, Thirumurugan S, Reddy DS, Anbalagan K, SubbiahPandi A - Acta Crystallogr E Crystallogr Commun (2015)

The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384566&req=5

Fap1: The molecular structure of the title compound with displacement ellipsoids drawn at the 30% probability level.
Bottom Line: The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron.The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio.C-H⋯Cl inter-actions also occur.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Physics, Pachaiyappa's College for Men, Kanchipuram 631 501, India.

ABSTRACT
The title compound, [ZnCl2(C8H11N)2], was synthesized by the reaction of zinc dichloride and 4-ethyl-aniline. The Zn(2+) cation is coordinated by two Cl(-) anions and the N atoms of two 4-ethyl-aniline ligands, forming a distorted Zn(N2Cl2) tetra-hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N-H⋯Cl hydrogen bonds link the mol-ecules into sheets perpendicular to the a axis. C-H⋯Cl inter-actions also occur.

No MeSH data available.


Related in: MedlinePlus