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Crystal structure of bis-[μ-meth-oxy(pyridin-2-yl)methano-lato-κ(3) N,O:O]bis[chlorido-copper(II)].

Boonlue S, Sirikulkajorn A, Chainok K - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: The racemic title compound, [Cu2(C7H8NO2)2Cl2], is composed of dinuclear mol-ecules in which meth-oxy(pyridin-2-yl)methano-late ligands bridge two symmetry-related Cu(II) ions.Each Cu(II) ion is coordinated in a square-planar geometry by one Cl atom, the N and O atoms of the bidentate ligand and the bridging O atom of the centrosymmetrically related bidentate ligand.The separation between the two Cu(II) atoms is 3.005 (1) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Naresuan University, Mueang, Phitsanulok 65000, Thailand.

ABSTRACT
The racemic title compound, [Cu2(C7H8NO2)2Cl2], is composed of dinuclear mol-ecules in which meth-oxy(pyridin-2-yl)methano-late ligands bridge two symmetry-related Cu(II) ions. Each Cu(II) ion is coordinated in a square-planar geometry by one Cl atom, the N and O atoms of the bidentate ligand and the bridging O atom of the centrosymmetrically related bidentate ligand. The separation between the two Cu(II) atoms is 3.005 (1) Å. In the crystal, non-classical C-H⋯O hydrogen bonds, weak π-π stacking [centroid-centroid distance = 4.073 (1) Å] and weak electrostatic Cu⋯Cl inter-actions [3.023 (1) Å] link the dinuclear mol-ecules into chains running parallel to the b axis. These chains are further connected by weak C-H⋯Cl hydrogen bonds directed approximately along the a axis, forming a three-dimensional supra-molecular network.

No MeSH data available.


Related in: MedlinePlus

A view of the dinuclear molecule of the title compound, showing the atom labelling. Displacement ellipsoids are drawn at the 50% probability level.
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Fap1: A view of the dinuclear molecule of the title compound, showing the atom labelling. Displacement ellipsoids are drawn at the 50% probability level.


Crystal structure of bis-[μ-meth-oxy(pyridin-2-yl)methano-lato-κ(3) N,O:O]bis[chlorido-copper(II)].

Boonlue S, Sirikulkajorn A, Chainok K - Acta Crystallogr E Crystallogr Commun (2015)

A view of the dinuclear molecule of the title compound, showing the atom labelling. Displacement ellipsoids are drawn at the 50% probability level.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384564&req=5

Fap1: A view of the dinuclear molecule of the title compound, showing the atom labelling. Displacement ellipsoids are drawn at the 50% probability level.
Bottom Line: The racemic title compound, [Cu2(C7H8NO2)2Cl2], is composed of dinuclear mol-ecules in which meth-oxy(pyridin-2-yl)methano-late ligands bridge two symmetry-related Cu(II) ions.Each Cu(II) ion is coordinated in a square-planar geometry by one Cl atom, the N and O atoms of the bidentate ligand and the bridging O atom of the centrosymmetrically related bidentate ligand.The separation between the two Cu(II) atoms is 3.005 (1) Å.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Faculty of Science, Naresuan University, Mueang, Phitsanulok 65000, Thailand.

ABSTRACT
The racemic title compound, [Cu2(C7H8NO2)2Cl2], is composed of dinuclear mol-ecules in which meth-oxy(pyridin-2-yl)methano-late ligands bridge two symmetry-related Cu(II) ions. Each Cu(II) ion is coordinated in a square-planar geometry by one Cl atom, the N and O atoms of the bidentate ligand and the bridging O atom of the centrosymmetrically related bidentate ligand. The separation between the two Cu(II) atoms is 3.005 (1) Å. In the crystal, non-classical C-H⋯O hydrogen bonds, weak π-π stacking [centroid-centroid distance = 4.073 (1) Å] and weak electrostatic Cu⋯Cl inter-actions [3.023 (1) Å] link the dinuclear mol-ecules into chains running parallel to the b axis. These chains are further connected by weak C-H⋯Cl hydrogen bonds directed approximately along the a axis, forming a three-dimensional supra-molecular network.

No MeSH data available.


Related in: MedlinePlus