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Crystal structure of aqua[N-(2-oxidobenzyl-κO)-l-leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N')-nickel(II) penta-hydrate.

Faizi MS, Sharkina NO - Acta Crystallogr E Crystallogr Commun (2015)

Bottom Line: In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the Ni(II) atom is in a distorted octa-hedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noic acid (HAMA) ligand and one water mol-ecule.The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio.In the crystal, the complex mol-ecules and solvate water mol-ecules are associated via O-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India.

ABSTRACT
In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the Ni(II) atom is in a distorted octa-hedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noic acid (HAMA) ligand and one water mol-ecule. The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio. In the crystal, the complex mol-ecules and solvate water mol-ecules are associated via O-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.


A view of the O—H⋯O hydrogen-bond inter­actions between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and carb­oxy­lic groups and solvate water mol­ecules in the crystal of the title compound (hydrogen bonds are shown as dashed lines; see Table 1 ▸ for details).
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fig2: A view of the O—H⋯O hydrogen-bond inter­actions between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and carb­oxy­lic groups and solvate water mol­ecules in the crystal of the title compound (hydrogen bonds are shown as dashed lines; see Table 1 ▸ for details).

Mentions: In the crystal packing, the complex mol­ecules and solvate water mol­ecules are associated via inter­molecular hydrogen bonds (Table 1 ▸ and Fig. 2 ▸) that involve O—H inter­actions of medium strength between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and the carb­oxy­lic groups and solvate water mol­ecules, forming a three-dimensional network (Fig. 3 ▸).


Crystal structure of aqua[N-(2-oxidobenzyl-κO)-l-leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N')-nickel(II) penta-hydrate.

Faizi MS, Sharkina NO - Acta Crystallogr E Crystallogr Commun (2015)

A view of the O—H⋯O hydrogen-bond inter­actions between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and carb­oxy­lic groups and solvate water mol­ecules in the crystal of the title compound (hydrogen bonds are shown as dashed lines; see Table 1 ▸ for details).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4384555&req=5

fig2: A view of the O—H⋯O hydrogen-bond inter­actions between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and carb­oxy­lic groups and solvate water mol­ecules in the crystal of the title compound (hydrogen bonds are shown as dashed lines; see Table 1 ▸ for details).
Mentions: In the crystal packing, the complex mol­ecules and solvate water mol­ecules are associated via inter­molecular hydrogen bonds (Table 1 ▸ and Fig. 2 ▸) that involve O—H inter­actions of medium strength between the donor atoms of the water mol­ecules and acceptor oxygen atoms of the phenolic and the carb­oxy­lic groups and solvate water mol­ecules, forming a three-dimensional network (Fig. 3 ▸).

Bottom Line: In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the Ni(II) atom is in a distorted octa-hedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noic acid (HAMA) ligand and one water mol-ecule.The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio.In the crystal, the complex mol-ecules and solvate water mol-ecules are associated via O-H⋯O hydrogen bonds into a three-dimensional network.

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India.

ABSTRACT
In the title compound, [Ni(C13H17NO3)(C12H8N2)(H2O)]·5H2O, the Ni(II) atom is in a distorted octa-hedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hy-droxy-benz-yl)amino]-4-methyl-penta-noic acid (HAMA) ligand and one water mol-ecule. The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio. In the crystal, the complex mol-ecules and solvate water mol-ecules are associated via O-H⋯O hydrogen bonds into a three-dimensional network.

No MeSH data available.