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The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus

Reaction of P4S3 with in situ generated phosphenium ion PI2+; A = Al(OC(CF3)3)4.
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sch15: Reaction of P4S3 with in situ generated phosphenium ion PI2+; A = Al(OC(CF3)3)4.

Mentions: A multitude of phosphorus-chalcogenides have been characterized to date and many of their structural motifs are displayed even in undergraduate textbooks.61 However, until recently, only very few examples of polyphosphorus-chalcogen cations were known which was due to the lack of established synthetic routes for their preparation. To the best of our knowledge only three distinct protocols have been reported so far. The first is based on the reaction of P4S3 with in situ generated phosphenium ion PI2+ (Scheme 15).44b


The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Reaction of P4S3 with in situ generated phosphenium ion PI2+; A = Al(OC(CF3)3)4.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4288811&req=5

sch15: Reaction of P4S3 with in situ generated phosphenium ion PI2+; A = Al(OC(CF3)3)4.
Mentions: A multitude of phosphorus-chalcogenides have been characterized to date and many of their structural motifs are displayed even in undergraduate textbooks.61 However, until recently, only very few examples of polyphosphorus-chalcogen cations were known which was due to the lack of established synthetic routes for their preparation. To the best of our knowledge only three distinct protocols have been reported so far. The first is based on the reaction of P4S3 with in situ generated phosphenium ion PI2+ (Scheme 15).44b

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus