Limits...
The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus

Preparation of compounds 36a–h[GaCl4] from P4, R2PCl and GaCl3 in fluorobenzene (R = aryl) or according to a solvent free approach (R = alkyl) and species 37 and 38+ commonly observed in mixtures of R2PCl and GaCl3.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4288811&req=5

sch10: Preparation of compounds 36a–h[GaCl4] from P4, R2PCl and GaCl3 in fluorobenzene (R = aryl) or according to a solvent free approach (R = alkyl) and species 37 and 38+ commonly observed in mixtures of R2PCl and GaCl3.

Mentions: R2P5[GaCl4] cage compounds 36[GaCl4] featuring two alkyl- or aryl-substituents R are obtained in high yield via the reaction of chlorophosphanes R2PCl, GaCl3 and P4 (Scheme 10).49


The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Preparation of compounds 36a–h[GaCl4] from P4, R2PCl and GaCl3 in fluorobenzene (R = aryl) or according to a solvent free approach (R = alkyl) and species 37 and 38+ commonly observed in mixtures of R2PCl and GaCl3.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4288811&req=5

sch10: Preparation of compounds 36a–h[GaCl4] from P4, R2PCl and GaCl3 in fluorobenzene (R = aryl) or according to a solvent free approach (R = alkyl) and species 37 and 38+ commonly observed in mixtures of R2PCl and GaCl3.
Mentions: R2P5[GaCl4] cage compounds 36[GaCl4] featuring two alkyl- or aryl-substituents R are obtained in high yield via the reaction of chlorophosphanes R2PCl, GaCl3 and P4 (Scheme 10).49

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus