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The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus

Influence of the steric demand of substituents R on the structural parameters of the P5+-cage core in cations of type 36+; upon increasing the steric demand of R green arrows indicate increasing angles and distances and red arrows indicate declining angles and distances.
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fig10: Influence of the steric demand of substituents R on the structural parameters of the P5+-cage core in cations of type 36+; upon increasing the steric demand of R green arrows indicate increasing angles and distances and red arrows indicate declining angles and distances.

Mentions: The molecular structures of all compounds of the series 36a–h[GaCl4] were determined by single crystal X-ray structure determination. This allowed for an in-depth evaluation of the influence of substituents of distinct steric demand on the structural parameters of the P5-cage in the solid state (Fig. 10).


The chemistry of cationic polyphosphorus cages--syntheses, structure and reactivity.

Holthausen MH, Weigand JJ - Chem Soc Rev (2014)

Influence of the steric demand of substituents R on the structural parameters of the P5+-cage core in cations of type 36+; upon increasing the steric demand of R green arrows indicate increasing angles and distances and red arrows indicate declining angles and distances.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4288811&req=5

fig10: Influence of the steric demand of substituents R on the structural parameters of the P5+-cage core in cations of type 36+; upon increasing the steric demand of R green arrows indicate increasing angles and distances and red arrows indicate declining angles and distances.
Mentions: The molecular structures of all compounds of the series 36a–h[GaCl4] were determined by single crystal X-ray structure determination. This allowed for an in-depth evaluation of the influence of substituents of distinct steric demand on the structural parameters of the P5-cage in the solid state (Fig. 10).

Bottom Line: The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages.The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted.In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds.

View Article: PubMed Central - PubMed

Affiliation: Department of Chemistry, University of Toronto, Toronto, Canada. m.holthausen@utoronto.ca.

ABSTRACT
The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P4, and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P4 and its transformation into (organo-)phosphorus compounds and materials of added value.

No MeSH data available.


Related in: MedlinePlus