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Functional Conducting Polymers via Thiol-ene Chemistry.

Feldman KE, Martin DC - Biosensors (Basel) (2012)

Bottom Line: We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains.These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively.This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

View Article: PubMed Central - PubMed

Affiliation: Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA. katiefeldman0@gmail.com.

ABSTRACT
We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

No MeSH data available.


Synthesis of side-chain functionalized ProDOT derivatives.
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Related In: Results  -  Collection

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biosensors-02-00305-scheme1: Synthesis of side-chain functionalized ProDOT derivatives.


Functional Conducting Polymers via Thiol-ene Chemistry.

Feldman KE, Martin DC - Biosensors (Basel) (2012)

Synthesis of side-chain functionalized ProDOT derivatives.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4263549&req=5

biosensors-02-00305-scheme1: Synthesis of side-chain functionalized ProDOT derivatives.
Bottom Line: We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains.These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively.This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

View Article: PubMed Central - PubMed

Affiliation: Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA. katiefeldman0@gmail.com.

ABSTRACT
We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.

No MeSH data available.