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Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

Werner J, Reinert T, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2] n , the Cd(II) cations are coordinated in a slightly distorted octa-hedral geometry by one 3-tert-butyl-pyridine ligand, one 4-tert-butyl-pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio-cyanate ligands, all of which are in general positions.These μ-1,3-bridging thio-cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2] n , the Cd(II) cations are coordinated in a slightly distorted octa-hedral geometry by one 3-tert-butyl-pyridine ligand, one 4-tert-butyl-pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio-cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio-cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

No MeSH data available.


: Crystal structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. Symmetry code: i: (x, y+1, z); ii: (x, y-1, z).
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Fap1: : Crystal structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. Symmetry code: i: (x, y+1, z); ii: (x, y-1, z).


Crystal structure of catena-poly[[(3-tert-butyl-pyridine-κN)(4-tert-butyl-pyridine-κN)cadmium]-di-μ-thio-cyanato-κ(2) N:S;κ(2) S:N].

Werner J, Reinert T, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2014)

: Crystal structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. Symmetry code: i: (x, y+1, z); ii: (x, y-1, z).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257453&req=5

Fap1: : Crystal structure of the title compound. Displacement ellipsoids are drawn at the 50% probability level. Symmetry code: i: (x, y+1, z); ii: (x, y-1, z).
Bottom Line: In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2] n , the Cd(II) cations are coordinated in a slightly distorted octa-hedral geometry by one 3-tert-butyl-pyridine ligand, one 4-tert-butyl-pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio-cyanate ligands, all of which are in general positions.These μ-1,3-bridging thio-cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Strasse 2, 24118 Kiel, Germany.

ABSTRACT
In the crystal structure of the title compound, [Cd(NCS)2(C9H13N)2] n , the Cd(II) cations are coordinated in a slightly distorted octa-hedral geometry by one 3-tert-butyl-pyridine ligand, one 4-tert-butyl-pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio-cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio-cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

No MeSH data available.