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Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-κ(2) N,O}zinc di-chloro-methane mono-solvate.

Hao YZ - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed.In the crystal, the complex mol-ecules stack into columns along the a axis.Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

View Article: PubMed Central - HTML - PubMed

Affiliation: Guangzhou Super-Dragon Engineering Plastics Co. Ltd, People's Republic of China ; Guangzhou Engineering, Technology Research Center, Guangzhou 510900, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl-aldehyde imine ligands, leading to a distorted tetra-hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed. In the crystal, the complex mol-ecules stack into columns along the a axis. Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

No MeSH data available.


View of the crystal structure of title compound; H atoms are omitted for clarity.
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Fap2: View of the crystal structure of title compound; H atoms are omitted for clarity.


Crystal structure of bis-{2,4-di-tert-butyl-6-[(iso-propyl-imino)-meth-yl]phenolato-κ(2) N,O}zinc di-chloro-methane mono-solvate.

Hao YZ - Acta Crystallogr Sect E Struct Rep Online (2014)

View of the crystal structure of title compound; H atoms are omitted for clarity.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257443&req=5

Fap2: View of the crystal structure of title compound; H atoms are omitted for clarity.
Bottom Line: Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed.In the crystal, the complex mol-ecules stack into columns along the a axis.Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

View Article: PubMed Central - HTML - PubMed

Affiliation: Guangzhou Super-Dragon Engineering Plastics Co. Ltd, People's Republic of China ; Guangzhou Engineering, Technology Research Center, Guangzhou 510900, People's Republic of China.

ABSTRACT
In the title compound, [Zn(C18H28NO)2]·CH2Cl2, the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl-aldehyde imine ligands, leading to a distorted tetra-hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra-molecular non-classical C-H⋯O hydrogen-bonding inter-actions are observed. In the crystal, the complex mol-ecules stack into columns along the a axis. Di-chloro-methane solvent mol-ecules are situated in the voids of this arrangement.

No MeSH data available.