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Crystal structure of piperidinium 4-nitro-phenolate.

Sowmya NS, Sampathkrishnan S, Sudhahar S, Chakkaravarthi G, Kumar RM - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom.In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring.In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100].

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Affiliation: Department of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, India.

ABSTRACT
In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C-H⋯π inter-actions, forming sheets lying parallel to (001).

No MeSH data available.


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The crystal packing of the title salt, viewed along the b axis. Hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; H atoms not involved in hydrogen bonding have been omitted for clarity).
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fig2: The crystal packing of the title salt, viewed along the b axis. Hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; H atoms not involved in hydrogen bonding have been omitted for clarity).

Mentions: In the crystal, adjacent cations and anions are linked by the N—H⋯O hydrogen bonds, which generate infinite chains along [100] (see Table 1 ▶ and Fig. 2 ▶). The chains are linked by C—H⋯π inter­actions, forming sheets lying parallel to the ab plane (Table 1 ▶).


Crystal structure of piperidinium 4-nitro-phenolate.

Sowmya NS, Sampathkrishnan S, Sudhahar S, Chakkaravarthi G, Kumar RM - Acta Crystallogr Sect E Struct Rep Online (2014)

The crystal packing of the title salt, viewed along the b axis. Hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; H atoms not involved in hydrogen bonding have been omitted for clarity).
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257431&req=5

fig2: The crystal packing of the title salt, viewed along the b axis. Hydrogen bonds are shown as dashed lines (see Table 1 ▶ for details; H atoms not involved in hydrogen bonding have been omitted for clarity).
Mentions: In the crystal, adjacent cations and anions are linked by the N—H⋯O hydrogen bonds, which generate infinite chains along [100] (see Table 1 ▶ and Fig. 2 ▶). The chains are linked by C—H⋯π inter­actions, forming sheets lying parallel to the ab plane (Table 1 ▶).

Bottom Line: In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom.In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring.In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100].

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Applied Physics, Sri Venkateswara College of Engineering, Chennai 602 117, India.

ABSTRACT
In the title mol-ecular salt, C5H12N(+)·C6H4NO3 (-), the piperidine ring adopts a chair conformation and the cation is protonated at the N atom. In the anion, the nitro group is twisted at an angle of 10.30 (11)° with respect to the attached benzene ring. In the crystal, N-H⋯O hydrogen bonds link adjacent anions and cations into infinite chains propagating along [100]. The chains are linked by C-H⋯π inter-actions, forming sheets lying parallel to (001).

No MeSH data available.


Related in: MedlinePlus