Limits...
Crystal structure of tin(II) perchlorate trihydrate.

Hennings E, Schmidt H, Köhler M, Voigt W - Acta Crystallogr Sect E Struct Rep Online (2014)

Bottom Line: The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid.Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes.In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets.

View Article: PubMed Central - HTML - PubMed

Affiliation: TU Bergakademie Freiberg, Institute of Inorganic Chemistry, Leipziger Strasse 29, D-09596 Freiberg, Germany.

ABSTRACT
The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid. Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets.

No MeSH data available.


The unit-cell packing in tin(II) perchlorate trihydrate with the ions shown in polyhedral representation.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC4257428&req=5

fig2: The unit-cell packing in tin(II) perchlorate trihydrate with the ions shown in polyhedral representation.

Mentions: The different coordination of Sn2+ in comparison with Ba2+ is caused by the lone-pair effect. It requires more space, so the distance to the next oxygen atoms is larger than in the barium salt structure. The perchlorate tetra­hedra are connected by O—H⋯O hydrogen bonds (Table 2 ▶) with the water mol­ecules coordinated at the tin atoms (Figs. 2 ▶ and 3 ▶), forming sheets parallel to (001).


Crystal structure of tin(II) perchlorate trihydrate.

Hennings E, Schmidt H, Köhler M, Voigt W - Acta Crystallogr Sect E Struct Rep Online (2014)

The unit-cell packing in tin(II) perchlorate trihydrate with the ions shown in polyhedral representation.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC4257428&req=5

fig2: The unit-cell packing in tin(II) perchlorate trihydrate with the ions shown in polyhedral representation.
Mentions: The different coordination of Sn2+ in comparison with Ba2+ is caused by the lone-pair effect. It requires more space, so the distance to the next oxygen atoms is larger than in the barium salt structure. The perchlorate tetra­hedra are connected by O—H⋯O hydrogen bonds (Table 2 ▶) with the water mol­ecules coordinated at the tin atoms (Figs. 2 ▶ and 3 ▶), forming sheets parallel to (001).

Bottom Line: The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid.Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes.In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets.

View Article: PubMed Central - HTML - PubMed

Affiliation: TU Bergakademie Freiberg, Institute of Inorganic Chemistry, Leipziger Strasse 29, D-09596 Freiberg, Germany.

ABSTRACT
The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlorate hexa-hydrate and metallic tin in perchloric acid. Both the trigonal-pyramidal [Sn(H2O)3](2+) cations and tetra-hedral perchlorate anions lie on crystallographic threefold axes. In the crystal, the cations are linked to the anions by O-H⋯O hydrogen bonds, generating (001) sheets.

No MeSH data available.